ATMOSPHERIC CHEMISTRY OF PEROXIDES - A REVIEW

被引:232
作者
GUNZ, DW [1 ]
HOFFMANN, MR [1 ]
机构
[1] CALTECH, WM KECK LABS 13878, PASADENA, CA 91125 USA
来源
ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS | 1990年 / 24卷 / 07期
关键词
acid formation; Atmospheric peroxide research; free radical reactions; hydrogen peroxide; hydroperoxy radical; nitric acid; organic hydroperoxides; sulfuric acid;
D O I
10.1016/0960-1686(90)90496-A
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Inorganic and organic peroxides have become the focus of increased attention by atmospheric chemists during the last decade. Hydrogen peroxide serves as an important link between gas phase radicals and aqueous phase chemistry in the atmosphere. As an important aqueous phase oxidant of S(IV), H2O2 plays a major role in the acidification of clouds, fogs, dew and rain. Several studies have indicated that peroxides and their precursor radicals cause damage to a variety of plant tissue. In this article we review analytical techniques, discuss and review the various sources of peroxides in the gas and aqueous phases and examine their reactions with S(IV) and N(III). © 1990.
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页码:1601 / 1633
页数:33
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