REACTIONS OF THE DIRHENIUM(III) CARBOXYLATE COMPLEXES RE2(O2CR)2X4L2 (R = ME, ET, X = CL, BR, L = H2O, 4-MEPY) WITH 2-HYDROXYPYRIDINE (HHP) AND 2-HYDROXY-6-METHYLPYRIDINE (HMHP) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF COMPLEXES OF THE TYPE-RE2(HP)2X4.HHP AND TYPE-RE2(MHP)2X4.HMHP AND HYDROLYSIS OF NITRILES (R'CN) TO GIVE THE CARBOXYLATE-BRIDGED SPECIES RE2(MU-O2CR')(MHP)2X3E

被引：18

作者：

CUTLER, AR ^{[1
]}

ESJORNSON, SMV ^{[1
]}

FANWICK, PE ^{[1
]}

WALTON, RA ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1988年 / 27卷 / 02期

关键词：

D O I：

10.1021/ic00275a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：287 / 292

页数：6

共 18 条

[1]

Barder T.J., 1985, INORG SYN, V23, P116

[2] REDUCTIVE COUPLING OF PERRHENATE TO FORM THE OCTACHLORODIRHENATE(III) ANION - A NEW, CONVENIENT, AND HIGH-YIELD SYNTHETIC PROCEDURE [J].

BARDER, TJ ;

WALTON, RA .

INORGANIC CHEMISTRY, 1982, 21 (06) :2510-2511

[3] STEREOCHEMICAL CONTROL OF AXIAL BINDING FOR DIRHODIUM(II) COMPLEXES [J].

BERRY, M ;

GARNER, CD ;

HILLIER, IH ;

CLEGG, W .

INORGANICA CHIMICA ACTA-LETTERS, 1980, 45 (05) :L209-L210

[4] A NOVEL DISPROPORTIONATION REACTION THAT OCCURS AT A MULTIPLY BONDED DIMETAL CENTER - THE ISOLATION OF DIRHENIUM(IV,II) ALKOXIDE COMPLEXES OF THE TYPE (RO)2CL2RERECL2(PPH3)2 (R = ME, ET, OR N-PR) [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

CUTLER, AR ;

TETRICK, SM ;

WALTON, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (16) :4795-4796

[5] SYNTHESES, MOLECULAR-STRUCTURES, AND PROPERTIES OF 2 POLAR DIRUTHENIUM(II,III) COMPLEXES OF 2-HYDROXYPYRIDINE AND 2-ANILINOPYRIDINE [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA .

INORGANIC CHEMISTRY, 1985, 24 (02) :172-177

[6] REACTIVITY OF THE DIRHENIUM(III) CARBOXYLATE COMPLEXES RE2(O2CCH3)2CL4(H2O)2 OR RE2(O2CCH3)2BR4(H2O)2 TOWARD MONODENTATE PHOSPHINES - A NOVEL DISPROPORTIONATION REACTION LEADING TO DIRHENIUM(IV,II) ALKOXIDE COMPLEXES OF THE TYPE (RO)2X2REREX2(PPH3)2 (X = CL OR BR - R = ME, ET, OR PR) [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

CUTLER, AR ;

WALTON, RA .

INORGANIC CHEMISTRY, 1986, 25 (20) :3619-3624

[7]

Cotton F. A., 1982, MULTIPLE BONDS METAL

[8]

COTTON FA, 1985, STRUCT BOND, V62, P1

[9] PREPARATION AND STRUCTURE OF DICHLOROTETRAKIS(ORTHO-OXYPYRIDINE)DIRHENIUM(III) [J].

COTTON, FA ;

GAGE, LD .

INORGANIC CHEMISTRY, 1979, 18 (06) :1716-1718

[10] SOME REACTIONS OF OCTAHALODIRHENATE(3) IONS .3. STABILITY OF RHENIUM-RHENIUM BOND TOWARD OXYGEN AND SULFUR DONORS [J].

COTTON, FA ;

OLDHAM, C ;

WALTON, RA .

INORGANIC CHEMISTRY, 1967, 6 (02) :214-&

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