HIGH-COORDINATION NUMBER FLUORO-ANIONS AND OXOFLUORO-ANIONS - IF6O-, TEF6O2-, TEF7-, IF8- AND TEF82-

被引：53

作者：

CHRISTE, KO ^{[1
]}

SANDERS, JCP ^{[1
]}

SCHROBILGEN, GJ ^{[1
]}

WILSON, WW ^{[1
]}

机构：

[1] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 13期

关键词：

BRF6;

D O I：

10.1039/c39910000837

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel hypervalent, highly coordinated, high-oxidation state anions IF6O-, TeF6O2-, TeF7-, IF8- and TeF8(2-) have been synthesized in anhydrous MeCN using anhydrous N(Me)4+F- as the fluoride ion source; the anions have been characterized by NMR and vibrational spectroscopy and represent novel examples of seven and eight-coordinate species having symmetries C5v (IF6O-, TeF6O2-), D5h (TeF7-) and D4d (IF8-, TeF8(2-)).

引用

页码：837 / 840

页数：4

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