COMPLEXES OF POLYHYDRO-2,2'-BIPYRIDINES WITH MOLYBDENUM AND TUNGSTEN CARBONYLS

被引：5

作者：

BOKORNY, S ^{[1
]}

CONNOR, JA ^{[1
]}

KASPAR, H ^{[1
]}

机构：

[1] UNIV KENT,CHEM LAB,CANTERBURY CT2 7NH,KENT,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 471卷 / 1-2期

关键词：

MOLYBDENUM; TUNGSTEN; SOLVATOCHROMISM; CHARGE TRANSFER; ELECTRONIC; BIPYRIDINE;

D O I：

10.1016/0022-328X(94)88119-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of 2,2'-bipyridine with tin in hydrochloric acid produces both 2-(2'-piperidinyl) pyridine and (1,2,3,6-tetrahydro)-2,2'-bipyridine, which have been characterised by (IR, NMR, and UV) spectroscopy. Tetracarbonyl-molybdenum and -tungsten complexes of these ligands exhibit a solvatochromic behaviour very similar to that of the analogous 2,2'-bipyridine complexes.

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页码：157 / 160

页数：4

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