PHOTOINITIATED THERMOLYSIS OF POLY(PHENYLENEVINYLENE) PRECURSOR AND PHOTOCHEMICAL DOPING OF POLY(PHENYLENEVINYLENE)

被引：8

作者：

CHO, I

KIM, JB

LEE, SH

机构：

[1] Department of Advanced Materials Engineering, Korea Advanced Institute of Science and Technology, Seoul, 130-650, P.O. Box 201, Chongyangri

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 11期

关键词：

D O I：

10.1002/marc.1995.030161111

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photoinitiated elimination of methoxy groups of poly(p-phenylene-1-methoxyethylene) and the photochemical doping of the resulting poly(phenylenevinylene) (PPV) were investigated. Upon irradiation and then heat treatment at 150 degrees C, poly(p-phenylene-1-methoxyethylene) containing triphenylsulfonium hexafluoroantimonate was converted to PPV. The resulting PPV was observed to be conductive, and its conductivity was 10(-2)-10(-3) S/cm. By a lithographic procedure, we produced a conducting pattern doped photochemically in a nonconjugated poly(p-phenylene-1-methoxyethylene) matrix.

引用

页码：851 / 854

页数：4

共 7 条

[1] BRUN PL, 1992, J CHEM SOC P1, P3225
[2] PHOTOINITIATED DOPING OF POLYACETYLENE
CLARKE, TC
KROUNBI, MT
LEE, VY
STREET, GB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (08) : 384 - 385
[3] CRIVELLO JV, 1984, ACS SYM SER, V242, P3
[4] SYNTHESIS OF POLY(2,5-DIMETHOXY-PARA-PHENYLENEVINYLENE) FILM THROUGH A NEW PRECURSOR POLYMER
MOMII, T
TOKITO, S
TSUTSUI, T
SAITO, S
[J]. CHEMISTRY LETTERS, 1988, (07) : 1201 - 1204
[5] Wessling R.A., 1968, [No title captured], Patent No. 3401152
[6] WESSLING RA, 1985, J POLYM SCI POLYM S, V72, P55
[7] WESSLING RA, 1972, Patent No. 3705677

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