THE INTERCONVERSION OF ADSORBED METHANOL FRAGMENTS ON PLATINUM AT CATHODIC POTENTIALS

被引：2

作者：

CHRISTENSEN, PA ^{[1
]}

HAMNETT, A ^{[1
]}

POTTER, RJ ^{[1
]}

机构：

[1] JOHNSON MATTHEY TECHNOL CTR, READING, ENGLAND

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1002/bbpc.19900940931

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of methanol at a platinum electrode in neutral sulphate solution was investigated using in-situ FTIR. Hitherto unreported interconversion between various adsorbed carbonyl species was observed at cathodic potentials, this conversion being driven by the formation of strongly adsorbed hydride.

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页码：1034 / 1038

页数：5

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