THE ELECTRONIC-STRUCTURE OF VO(5-H-SALEN)VO(5-OME-SALEN), VO(S-OH-SALEN), VO(5-CL-SALEN), VO(5-BR-SALEN), VO(5-NO2-SALEN)

被引：5

作者：

CHENG, SH ^{[1
]}

SHEEN, SR ^{[1
]}

CHENG, CP ^{[1
]}

CHANG, CT ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN

来源：

INORGANICA CHIMICA ACTA | 1990年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)84657-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The vanadyl complexes of the derivatives of salicylaldiimine, VO(5-X-salen), where X = H, OMe, OH, Cl, Br and NO2, are prepared and their electronic spectra measured. A fairly good relation can be drawn between the LMCT band energies and the Hammett parameters. The solvent effects upon the electronic and EPR spectra are also ascertained. © 1990.

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页码：21 / 24

页数：4

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