H-1 NUCLEAR-MAGNETIC-RESONANCE STUDIES OF THE REDUCTION OF PARAMAGNETIC IRON(III) ALKYL PORPHYRIN COMPLEXES TO DIAMAGNETIC IRON(II) ALKYL COMPLEXES

被引：28

作者：

BALCH, AL ^{[1
]}

CORNMAN, CR ^{[1
]}

SAFARI, N ^{[1
]}

LATOSGRAZYNSKI, L ^{[1
]}

机构：

[1] WROCLAW B BEIRUT UNIV,DEPT CHEM,PL-50137 WROCLAW,POLAND

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 09期

关键词：

D O I：

10.1021/om00159a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (TPP)FeIIICl in dichloromethane with LiHBEt3 yields (TPP)FeIIIEt.15 Reduction of (TPP)- FeIIIR to [(TPP)FeIIR]- (R = n-propyl, ethyl) by either LiHBEt3 or KHB(i-Bu)3 can be accomplished in benzene/ tetrahydrofuran solution, where electron exchange between the iron(III) and iron(II) alkyls is rapid. [(TPP)FeIIR]- is diamagnetic and is reoxidized by dioxygen to (TPP)FeIIIR. © 1990, American Chemical Society. All rights reserved.

引用

页码：2420 / 2421

页数：2

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