NOVEL DINUCLEAR DIHYDRIDE COMPLEXES OF RUTHENIUM CONTAINING BRIDGING CARBOXYLATE LIGANDS

被引：25

作者：

SUZUKI, H

KAKIGANO, T

IGARASHI, M

TANAKA, M

MOROOKA, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000283

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear tetrahydride-bridged ruthenium complex (eta-5-C5Me5)Ru(mu-H)4Ru(eta-5-C5Me5) reacts with carboxylic acid RCO2H (R = H, Me, CF3, C6H5, adamantyl) in tetrahydrofuran (thf) to afford the novel dinuclear dihydride complexes (eta-5-C5Me5)Ru(mu-H)2(mu-RCO2)2Ru(eta-5-C5Me5) containing two bridging carboxylate ligands, the reactivities and the X-ray crystal structure of which are also reported.

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页码：283 / 285

页数：3

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