FORMAL [2+2+1] AND [4+1] CYCLOADDITIONS OF ELECTRON-POOR ALKENES TO PENTACARBONYL [(N,N-DIMETHYLAMINO)METHYLENE]CHROMIUM

被引：40

作者：

SIERRA, MA ^{[1
]}

SODERBERG, B ^{[1
]}

LANDER, PA ^{[1
]}

HEGEDUS, LS ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 09期

关键词：

D O I：

10.1021/om00033a057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methyl acrylate and acrylonitrile underwent a formal [2+2+1] cycloaddition with pentacarbonyl[(N,N-dimethylamino)methylene]chromium to give trisubstituted cyclopentanes in modest yield. Methyl sorbate underwent a formal [4+1] cycloaddition with the same complex to produce the trisubstituted cyclopentene. A number of other conjugated enones failed to undergo this cyclization.

引用

页码：3769 / 3771

页数：3

共 21 条

[1] SYNTHESIS OF AMINO-BETA-LACTAMS BY THE PHOTOLYTIC REACTION OF IMINES WITH PENTACARBONYL[(DIBENZYLAMINO)CARBENE]CHROMIUM(0)
BOREL, C
HEGEDUS, LS
KREBS, J
SATOH, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (04) : 1101 - 1105
[2] BUCHERT M, 1992, CHEM BER, V25, P2723
[3] SYNTHESIS OF A CHELATED TUNGSTEN CARBENE ALKENE COMPLEX AND ITS CONVERSION TO A CYCLOPROPANE
CASEY, CP
VOLLENDORF, NW
HALLER, KJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) : 3754 - 3764
[4] INTRAMOLECULAR CYCLOPROPANATION AND OLEFIN METATHESIS REACTIONS OF (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4-PARA-CH3
CASEY, CP
HORNUNG, NL
KOSAR, WP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) : 4908 - 4916
[5] REACTION OF AMINOCARBENE COMPLEXES OF CHROMIUM WITH ALKYNES .1. FORMATION AND REARRANGEMENT OF KETENE AND NITROGEN YLIDE COMPLEXES
CHELAIN, E
GOUMONT, R
HAMON, L
PARLIER, A
RUDLER, M
RUDLER, H
DARAN, JC
VAISSERMANN, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8088 - 8098
[6] TRANSITION-METAL CARBENE COMPLEXES .42. SYNTHESIS OF CYCLOPROPANE DERIVATIVES FROM ALPHA,BETA-UNSATURATED ALKYL CARBOXYLATES WITH AID OF TRANSITION-METAL CARBONYL CARBENE COMPLEXES
DOTZ, KH
FISCHER, EO
[J]. CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (04): : 1356 - &
[7] TRANSITION-METAL CARBENE COMPLEXES .51. SYNTHESIS OF CYCLOPROPANE DERIVATIVES FROM VINYL ETHERS WITH AID OF TRANSITION-METAL CARBONYL CARBENE COMPLEXES
FISCHER, EO
DOTZ, KH
[J]. CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (12): : 3966 - &
[8] TRANSITION METAL CARBENE COMPLEXES .19. SYNTHESIS OF CYCLOPRPPANE DERIVATIVES WITH TRANSITION METAL CARBONYL CARBENE COMPLEXES
FISCHER, EO
DOTZ, KH
[J]. CHEMISCHE BERICHTE-RECUEIL, 1970, 103 (04): : 1273 - &
[9] GROTJAHN DB, 1991, SYNLETT, P381
[10] CYCLOPROPANATION OF UNACTIVATED 1,3-DIENES BY FISCHER CARBENE COMPLEXES
HARVEY, DF
LUND, KP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8916 - 8921

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