AN UNCONVENTIONAL INTERMOLECULAR 3-CENTER N-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-H2RE HYDROGEN-BOND IN CRYSTALLINE [REH5(PPH(3))(3)]CENTER-DOT-INDOLE-CENTER-DOT-C6H6

被引：190

作者：

WESSEL, J

LEE, JC

PERIS, E

YAP, GPA

FORTIN, JB

RICCI, JS

SINI, G

ALBINATI, A

KOETZLE, TF

EISENSTEIN, O

RHEINGOLD, AL

CRABTREE, RH

机构：

[1] YALE UNIV,DEPT CHEM,NEW HAVEN,CT 06511

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

[3] UNIV MILAN,INST PHARMACEUT CHEM,I-20131 MILAN,ITALY

[4] BROOKHAVEN NATL LAB,UPTON,NY 11973

[5] UNIV PARIS 11,CHIM THEOR LAB,URA 506,F-91405 ORSAY,FRANCE

[6] UNIV SO MAINE,PORTLAND,DORSET,ENGLAND

[7] BNL,UPTON,NY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

HYDROGEN BONDING; HYDRIDES; INDOLES; RHENIUM COMPOUNDS;

D O I：

10.1002/anie.199525071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three hydrogen atoms participate in the unusual hydrogen bond in complex 1, which is obtained when the rhenium compound is cocrystallized with indole from benzene. The structure of 1 was elucidated by means of neutron diffraction (HN … HM distances of 1.75 and 2.25 Å). The energy of the hydrogen bond was determined by IR spectroscopy (ΔH° = 4.3 ± 0.5 kcal mol−1). All these values were also reproduced by theoretical calculations. Indole may be a useful additive for crystal growing in general. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2507 / 2509

页数：3

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