PREPARATION AND PROPERTIES OF OXO-CENTERED TRINUCLEAR CHROMIUM(III) COMPLEXES WITH BRIDGING OPTICALLY-ACTIVE AMINO-ACIDS, [CR3(MU-3-O)(MU-O,O'-AMINO-ACID)6(H2O)3]7+

被引：13

作者：

KATO, H ^{[1
]}

NAKATA, K ^{[1
]}

NAGASAWA, A ^{[1
]}

YAMAGUCHI, T ^{[1
]}

SASAKI, Y ^{[1
]}

ITO, T ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, AOBA KU, SENDAI, MIYAGI 980, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 11期

关键词：

D O I：

10.1246/bcsj.64.3463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trinuclear chromium(III) complexes with optically active amino acids as bridging groups, [Cr3(mu-3-O)(mu-RCH(NH3)COO)6(H2O)3]X7 (R = CH3, (CH3)2CH, (CH3)2-CHCH2, C6H5CH2; X = Cl-, NO3-), were prepared, and the X-ray structure of the L-valine complex was determined. Their electronic spectra and magnetic moments are similar to those of analogous carboxylate-bridged trichromium(III) complexes.

引用

页码：3463 / 3465

页数：3

共 23 条

[1] PREPARATIONS AND CHARACTERIZATIONS OF MU-3-OXO-HEXAKIS(MU-2-CARBOXYLATOPYRIDINE-O,O)-TRIAQUATRICHROMIUM(III)PERCHLORATES [J].

BRADSHAW, JE ;

GROSSIE, DA ;

MULLICA, DF ;

PENNINGTON, DE .

INORGANICA CHIMICA ACTA, 1988, 141 (01) :41-47

[2] CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES [J].

CANNON, RD ;

WHITE, RP .

PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 :195-298

[3] CRYSTAL STRUCTURE OF A BASIC CHROMIUM ACETATE COMPOUND, OCR3(CH3COO)6.3H2O!+CL-.6H2O, HAVING FEEBLE PARAMAGNETISM [J].

CHANG, SC ;

JEFFREY, GA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 :673-&

[4] CRYSTAL-STRUCTURE OF [FECR2MU-3-O)(CH3COO)6(H2O)3]FECL4.2(CH3)2CO.CH3OH [J].

CLEGG, W ;

LAM, OM ;

STRAUGHAN, BP .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 90 (03) :L75-L76

[5] STRUCTURE OF A NOVEL MU-3-OXO-FE2(III)CRIII-GLYCINE COMPLEX [J].

CLEGG, W ;

LAM, OM ;

STRAUGHAN, BP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (06) :434-435

[6] ELECTRONIC-SPECTRUM OF TRINUCLEAR CHROMIUM(III) ACETATE [J].

DUBICKI, L ;

DAY, P .

INORGANIC CHEMISTRY, 1972, 11 (08) :1868-&

[7] CHEMISTRY OF POLYNUCLEAR COMPOUNDS .6. MAGNETIC PROPERTIES OF TRIMERIC CHROMIUM AND IRON CARBOXYLATES [J].

EARNSHAW, A ;

FIGGIS, BN ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (12) :1656-&

[8] THE DETERMINATION OF THE PARAMAGNETIC SUSCEPTIBILITY OF SUBSTANCES IN SOLUTION BY NUCLEAR MAGNETIC RESONANCE [J].

EVANS, DF .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (JUN) :2003-2005

[9]

FISHER VR, 1990, RUSS J INORG CHEM L, V35, P1298

[10] SYNTHESIS AND STRUCTURE OF A TRINUCLEAR CHROMIUM(III) - NICOTINIC-ACID COMPLEX [J].

GONZALEZVERGARA, E ;

HEGENAUER, J ;

SALTMAN, P ;

SABAT, M ;

IBERS, JA .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1982, 66 (04) :115-118

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