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FORMATION OF POLYCHLORINATED DIOXINS AND DIBENZOFURANS IN INCINERATION OF REFUSE DERIVED FUEL AND BIOSLUDGE

被引：18
作者：
HALONEN, I
TARHANEN, J
KOPSA, T
PALONEN, J
VILOKKI, H
RUUSKANEN, J
机构：
[1] LAITEOPTIMOINTI KY, SF-86710 KARSAMAKI, FINLAND
[2] AHLSTROM PYROPOWER, SF-48600 KARHULA, FINLAND
来源：
CHEMOSPHERE | 1993年 / 26卷 / 10期
关键词：
INCINERATION; FORMATION; FLUIDIZED BED COMBUSTION; RDF; BIOSLUDGE; CHLORINE; POLYCHLORINATED DIBENZODIOXINS AND POLYCHLORINATED DIBENZOFURANS;
D O I：
10.1016/0045-6535(93)90080-O
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 [工学]; 0830 [环境科学与工程];
摘要：
Incineration tests of biosludge and refuse derived fuel (RDF) were performed in a pilot scale circulating fluidized bed plant. Samples of chlorinated organic compounds were collected simultaneously at three different locations in the incinerator (temperatures 850, 250, and 140-degrees-C). Polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) concentrations formed in the furnace were higher in incineration tests of RDF than in incineration tests of biosludge mixtures. PCDD/PCDF formation at 850-degrees-C was observed to depend on chlorine content in the fuel. Post-formation of PCDD/PCDF compounds beyond the furnace was only observed in tests of RDF. Post-formation reactions were absent in tests of biosludge mixtures. Post-formation reactions were due to higher concentrations of metals, especially copper in RDF fuel.
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收藏
页码：1869 / 1880
页数：12
相关论文
共 21 条
[1]
DESOUSA F, 1989, TAPPI J, V72, P147
[2]
ERICKSON MD, CHEMOSPHERE, V19, P161
[3]
FANGMARK I, 1992, 12TH INT S DIOX REL, V8, P249
[4]
FORMATION OF CHLORINATED ORGANICS DURING SOLID-WASTE COMBUSTION [J].
GULLETT, BK ;
BRUCE, KR ;
BEACH, LO .
WASTE MANAGEMENT & RESEARCH, 1990, 8 (03) :203-214
[5]
THE EFFECT OF METAL-CATALYSTS ON THE FORMATION OF POLYCHLORINATED DIBENZO-PARA-DIOXIN AND POLYCHLORINATED DIBENZOFURAN PRECURSORS [J].
GULLETT, BK ;
BRUCE, KR ;
BEACH, LO .
CHEMOSPHERE, 1990, 20 (10-12) :1945-1952
[6]
CATALYTIC EFFECTS OF FLY-ASH FROM WASTE INCINERATION FACILITIES ON THE FORMATION AND DECOMPOSITION OF POLYCHLORINATED DIBENZO-PARA-DIOXINS AND POLYCHLORINATED DIBENZOFURANS [J].
HAGENMAIER, H ;
KRAFT, M ;
BRUNNER, H ;
HAAG, R .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1987, 21 (11) :1080-1084
[7]
SYNTHESIS OF POLYCHLORINATED DIOXINS OVER MSW INCINERATOR FLY-ASH TO IDENTIFY CATALYTIC SPECIES [J].
HINTON, WS ;
LANE, AM .
CHEMOSPHERE, 1991, 23 (07) :831-840
[8]
EXTRACTION AND CLEANUP PROCEDURE FOR POLYCHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS IN FLY-ASH FROM MUNICIPAL SOLID-WASTE INCINERATORS [J].
JIMENEZ, B ;
GONZALEZ, MJ ;
HERNANDEZ, LM .
JOURNAL OF CHROMATOGRAPHY, 1990, 523 :265-272
[9]
MODEL STUDIES OF POLYCHLORINATED DIBENZO-PARA-DIOXIN FORMATION DURING MUNICIPAL REFUSE INCINERATION [J].
KARASEK, FW ;
DICKSON, LC .
SCIENCE, 1987, 237 (4816) :754-756
[10]
KOPPONEN P, 1992, 12TH INT S DIOX REL, V10, P127
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