ELECTROCHEMICAL POLYMERIZATION OF 7-METHYL-THIONAPHTHENE-INDOLE

被引：5

作者：

CASALBOREMICELI, G

BEGGIATO, G

DIMARCO, PG

GERI, A

GIRO, G

机构：

[1] Instituto di Fotochimica e Radiazioni d'Alta Energia (FRAE) del Consiglio Nazionale delle Ricerche, Bologna, 40126

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1990年 / 20卷 / 03期

关键词：

D O I：

10.1007/BF01076058

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The effect of the methyl substituent in position 7 on the electrochemical polymerization of 7-methylthionaphthene-indole (7-methyl[1]benzothieno[3,2-b]indole; MTNI) was investigated. Acid-base equilibria involving the heterocyclic nitrogen were observed. The electrolytic synthesis of oxidized poly-MTNI is a process controlled by a protonation-deprotonation mechanism. The electrical conductivity of this material was measured. © 1990 Chapman and Hall Ltd.

引用

页码：468 / 474

页数：7

共 14 条

[1] ANODIC OXIDATION PATHWAYS OF CARBAZOLES .1. CARBAZOLE AND N-SUBSTITUTED DERIVATIVES [J].

AMBROSE, JF ;

NELSON, RF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (11) :1159-&

[2]

BEGGIATO G, 1987, B SOC CHIM FR, P301

[3] ELECTROCHEMICAL OXIDATION OF [1]BENZOTHIENO[3,2-B]INDOLE [J].

CASALBOREMICELI, G ;

BEGGIATO, G ;

EMMI, SS ;

GERI, A ;

RIGHETTI, B ;

DAOLIO, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1988, (07) :1231-1236

[4] ELECTROCHEMICAL OXIDATION AND POLYMERIZATION OF N-VINYL-THIONAPHTHENE-INDOLE [J].

CASALBOREMICELI, G ;

BEGGIATO, G ;

EMMI, SS ;

GERI, A ;

DAOLIO, S .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1988, 18 (06) :885-893

[5]

CASALBOREMICELI G, 1987, J APPL ELECTROCHEM, V17, P1111

[6]

CASALBOREMICELI G, 1986, SYNTHETIC MET, V15, P1

[7]

CASALBOREMICELI G, 1987, ANN CHIM-ROME, V77, P609

[8]

CAUQUIS C, 1977, B SOC CHIM FR, P34

[9]

CAUQUIS G, 1977, B SOC CHIM FR, P304

[10] THE ELECTROCHEMICAL OXIDATION OF POLY(N-VINYLCARBAZOLE) FILMS [J].

DAVIS, FJ ;

BLOCK, H ;

COMPTON, RG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (13) :890-892

← 1 2 →