MEDIATED ELECTROSYNTHESIS WITH CERIUM (IV) IN METHANESULPHONIC ACID

被引：65

作者：

SPOTNITZ, RM

KREH, RP

LUNDQUIST, JT

PRESS, PJ

机构：

[1] W. R. Grace and Company, Columbia, 21044, MD

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1990年 / 20卷 / 02期

关键词：

D O I：

10.1007/BF01033596

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Methanesulphonic acid has been found to solubilize the Ce(III)/Ce(IV) couple. This makes cerium mediated electrosynthesis practical for commercial production of several carbonyl compounds. Results are presented for the electrochemical generation of Ce(IV) in methanesulphonic acid and for naphthalene oxidation to 1,4-naphthoquinone using Ce(IV). © 1990 Chapman and Hall Ltd.

引用

页码：209 / 215

页数：7

共 20 条

[1]

ARANJO O, 1985, THESIS U ILLINOIS UR

[2]

CLARKE R, 1975, CHEM BR, V2, P59

[3]

COEURET F, 1984, ELEMENTS GENIE ELECT, P365

[4]

FEESS H, 1982, TECHNIQUES ELECTRO 3, P123

[5]

HO TL, 1973, SYNTHESIS-STUTTGART, P347

[6]

Ibl N., 1979, AICHE S SER, V75, P45

[7]

Kamakura T. K., 1985, US Patent, Patent No. 4530745

[8] SELECTIVE OXIDATIONS WITH CERIC METHANESULFONATE AND CERIC TRIFLUOROMETHANESULFONATE [J].

KREH, RP ;

SPOTNITZ, RM ;

LUNDQUIST, JT .

TETRAHEDRON LETTERS, 1987, 28 (10) :1067-1068

[9]

LONG JR, 1985, ALDRICHIM ACTA, V18, P87

[10]

OEHR K, 1982, Patent No. 1132996

← 1 2 →