ASYMMETRIC OXIDATION OF SULFIDES CATALYZED BY AN IRON COMPLEX OF C2-CHIRAL STRAPPED PORPHYRIN AS A CONCEPTUALLY NEW P-450 MODEL CATALYST

被引：51

作者：

CHIANG, LC ^{[1
]}

KONISHI, K ^{[1
]}

AIDA, T ^{[1
]}

INOUE, S ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT SYNTHET CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000254

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric oxidation of aryl sulfides by iodosobenzene has been achieved using the novel iron porphyrin catalysts derived from the antipodes of a C2-chiral 1,4-xylylene-strapped porphyrin, affording the corresponding sulfoxides in 18-71% enantiomeric excess.

引用

页码：254 / 256

页数：3

共 10 条

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