SOLID-STATE C-13 NUCLEAR-MAGNETIC-RESONANCE INVESTIGATIONS OF MOLECULAR-DYNAMICS IN CRYSTALLINE BENZENETRICARBONYL-CHROMIUM

被引：11

作者：

ALIEV, AE ^{[1
]}

HARRIS, KDM ^{[1
]}

GUILLAUME, F ^{[1
]}

BARRIE, PJ ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,SPECTROSCOPIE MOLEC & CRISTALLINE LAB,CNRS,URA 124,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 21期

关键词：

D O I：

10.1039/dt9940003193

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lineshape changes in the solid-state C-13 NMR spectrum of [Cr(eta6-C6H6)(CO)3] over the temperature range 203-393 K have been shown to be consistent with reorientation of the Cr(CO)3 unit (with free energy of activation estimated to be 70 +/- 5 kJ mol-1), and in-plane reorientation of the benzene molecule.

引用

页码：3193 / 3195

页数：3

共 17 条

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