SEPARATION AND PRECONCENTRATION OF ACTINIDES BY EXTRACTION CHROMATOGRAPHY USING A SUPPORTED LIQUID ANION-EXCHANGER - APPLICATION TO THE CHARACTERIZATION OF HIGH-LEVEL NUCLEAR WASTE SOLUTIONS

被引：398

作者：

HORWITZ, EP ^{[1
]}

DIETZ, ML ^{[1
]}

CHIARIZIA, R ^{[1
]}

DIAMOND, H ^{[1
]}

MAXWELL, SL ^{[1
]}

NELSON, MR ^{[1
]}

机构：

[1] WESTINGHOUSE SAVANNAH RIVER CO,AIKEN,SC 29809

来源：

ANALYTICA CHIMICA ACTA | 1995年 / 310卷 / 01期

关键词：

CHROMATOGRAPHY; ION EXCHANGE; PRECONCENTRATION; ACTINIDES; NUCLEAR WASTE;

D O I：

10.1016/0003-2670(95)00144-O

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel extraction chromatographic resin comprised of a quaternary amine-based liquid anion exchanger sorbed on an inert polymeric substrate for the sorption of actinides from nitric and hydrochloric acids is described. The resin is shown to exhibit preferential retention of tetravalent actinides over a wide range of acidities. The application of this material to the separation and preconcentration of selected actinides from high level nuclear waste solutions for subsequent determination is described.

引用

页码：63 / 78

页数：16

共 32 条

[1]

BLASEWITZ AG, 1983, TREATMENT HANDLING R

[2]

BRINKMAN UAT, 1972, J CHEM EDUC, V48, P245

[3] ACID DEPENDENCY OF THE EXTRACTION OF SELECTED METAL-IONS BY A STRONTIUM-SELECTIVE EXTRACTION CHROMATOGRAPHIC RESIN - CALCULATED VS EXPERIMENTAL CURVES [J].