EQUATION OF STATE FOR A FLUID OF HARD CONVEX-BODIES IN ANY NUMBER OF DIMENSIONS

被引：58

作者：

SONG, YH

MASON, EA

机构：

[1] Department of Chemistry, Brown University, Providence

来源：

PHYSICAL REVIEW A | 1990年 / 41卷 / 06期

关键词：

D O I：

10.1103/PhysRevA.41.3121

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

An equation of state is proposed for an isotropic fluid of hard convex bodies in any number of dimensions. In general, only knowledge of the first three virial coefficients is required. In three dimensions an approximation can be used that involves a single nonsphericity parameter. The result appears to be very accurate as far as it can be tested against available computer simulations. © 1990 The American Physical Society.

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页码：3121 / 3124

页数：4

相关论文

共 25 条

[1] RELATIONSHIP BETWEEN HARD-SPHERE FLUID AND FLUIDS WITH REALISTIC REPULSIVE FORCES [J].

ANDERSEN, HC ;

WEEKS, JD ;

CHANDLER, D .

PHYSICAL REVIEW A-GENERAL PHYSICS, 1971, 4 (04) :1597-+

[2] WHAT IS LIQUID - UNDERSTANDING STATES OF MATTER [J].

BARKER, JA ;

HENDERSON, D .

REVIEWS OF MODERN PHYSICS, 1976, 48 (04) :587-671

[3] P-V-T BEHAVIOR OF HARD BODY-FLUIDS - THEORY AND EXPERIMENT [J].

BOUBLIK, T ;

NEZBEDA, I .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1986, 51 (11) :2301-2432

[4] EQUATION OF STATE OF HARD CONVEX BODY-FLUIDS [J].

BOUBLIK, T .

MOLECULAR PHYSICS, 1981, 42 (01) :209-216

[5] EQUATIONS OF STATE OF HARD BODY-FLUIDS [J].

BOUBLIK, T .

MOLECULAR PHYSICS, 1986, 59 (02) :371-380

[6] STATISTICAL THERMODYNAMICS OF CONVEX MOLECULE FLUIDS [J].

BOUBLIK, T .

MOLECULAR PHYSICS, 1974, 27 (05) :1415-1427

[7] STRUCTURES OF MOLECULAR LIQUIDS [J].

CHANDLER, D .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1978, 29 :441-471

[8] EQUILIBRIUM STRUCTURE OF SIMPLE LIQUIDS [J].

CHANDLER, D ;

WEEKS, JD .

PHYSICAL REVIEW LETTERS, 1970, 25 (03) :149-&

[9] A NEW EQUATION OF STATE FOR POLAR AND NONPOLAR PURE FLUIDS [J].

CHUNG, TH ;

KHAN, MM ;

LEE, LL ;

STARLING, KE .

FLUID PHASE EQUILIBRIA, 1984, 17 (03) :351-372

[10] SCALED PARTICLE THEORY FOR MIXTURES OF HARD CONVEX PARTICLES [J].

GIBBONS, RM .

MOLECULAR PHYSICS, 1970, 18 (06) :809-&