BIOSYNTHESIS OF CATALPOL

被引：40

作者：

DAMTOFT, S

机构：

[1] Department of Organic Chemistry, The Technical University of Denmark, DK-2800 Lyngby

来源：

PHYTOCHEMISTRY | 1994年 / 35卷 / 05期

关键词：

SCUTELLARIA ALBIDA; LAMIACEAE; PAULOWNIA TOMENTOSA; BIGNONIACEAE; IRIDOID GLUCOSIDES; CATALPOL; TOMENTOSIDE; BIOSYNTHESIS; H-2; NMR;

D O I：

10.1016/S0031-9422(00)94819-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Feeding experiments with deuterium-labelled 8-epi-deoxyloganic acid, bartsioside and aucubin gave incorporation of all compounds into catalpol both in Scutellaria albida and Paulownia tomentosa. Dilution experiments with labelled 8-epi-deoxyloganic acid and unlabelled aucubin showed that aucubin is an intermediate in the biosynthesis of catalpol in these two species. 8-epi-Deoxyloganic acid was incorporated into tomentoside in P. tomentosa.

引用

收藏

页码：1187 / 1189

页数：3

相关论文

共 10 条

[1] A SYNTHESIS OF VITAMIN-A FROM CYCLOHEXANONE [J].

ATTENBURROW, J ;

CAMERON, AFB ;

CHAPMAN, JH ;

EVANS, RM ;

HEMS, BA ;

JANSEN, ABA ;

WALKER, T .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (MAR) :1094-1111

[2] SCALBIDOSIDE AND ALBIDOSIDE, 2 IRIDOID GLYCOSIDES FROM SCUTELLARIA-ALBIDA SUBSP COLCHICA [J].

CALIS, I ;

ERSOZ, T ;

SARACOGLU, I ;

STICHER, O .

PHYTOCHEMISTRY, 1993, 32 (05) :1213-1217

[3] TOMENTOSIDE AND 7-HYDROXYTOMENTOSIDE, 2 IRIDOID GLUCOSIDES FROM PAULOWNIA-TOMENTOSA [J].

DAMTOFT, S ;

JENSEN, SR .

PHYTOCHEMISTRY, 1993, 34 (06) :1636-1638

[4] BIOSYNTHESIS OF THE IRIDOIDS AUCUBIN AND ANTIRRINOSIDE FROM 8-EPI-DEOXYLOGANIC ACID [J].

DAMTOFT, S .

PHYTOCHEMISTRY, 1983, 22 (09) :1929-1930

[5] BIOSYNTHESIS OF LAMIIDE AND IPOLAMIIDE FROM 8-EPI-DEOXYLOGANIN STUDIED BY H-2 NMR-SPECTROSCOPY [J].

DAMTOFT, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (05) :228-229

[6] LATE STAGES IN THE BIOSYNTHESIS OF AUCUBIN IN SCROPHULARIA [J].

DAMTOFT, S ;

JENSEN, SR ;

JESSEN, JCU ;

KNUDSEN, TB .

PHYTOCHEMISTRY, 1993, 33 (05) :1089-1093

[7] BIOSYNTHESIS OF IRIDOID GLUCOSIDES IN LAMIUM-ALBUM [J].

DAMTOFT, S ;

JENSEN, SR ;

NIELSEN, BJ .

PHYTOCHEMISTRY, 1992, 31 (01) :135-137

[8]

INOUYE H, 1972, CHEM PHARM BULL, V20, P1287

[9]

Inouye H., 1986, PROG CHEM NAT PROD, V50, P169

[10]

JENSEN SR, 1975, BOT NOTISER, V128, P148