H-1 AND C-13 NMR CHARACTERIZATION OF NEW OLEUROPEIN AGLYCONES

被引：64

作者：

LIMIROLI, R

CONSONNI, R

OTTOLINA, G

MARSILIO, V

BIANCHI, G

ZETTA, L

机构：

[1] CNR,IST CHIM MACROMOLEC,NMR LAB,I-20133 MILAN,ITALY

[2] IST SPERIMENTALE ELAIOTECN,PESCARA,ITALY

[3] CNR,IST CHIM ORMONI,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 12期

关键词：

D O I：

10.1039/p19950001519

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enzymatic hydrolysis of oleuropein carried out in a NMR tube, gave two diastereoisomeric aglycones, which have been identified and characterized by proton and carbon NMR experiments in the same aqueous reaction medium. The stereostructures, assigned to the aglycones by NOESY spectroscopy and molecular dynamics calculation are those of two diastereoisomers, 4a and 4b.

引用

页码：1519 / 1523

页数：5

共 22 条

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