PHASE-TRANSITIONS AND IONIC-CONDUCTION IN 3D SKELETON PHOSPHATES LI3CR2(PO4)3, LI3FE2(PO4)3, NA3CR2(PO4)3, NA3FE2(PO4)3, AG3CR2(PO4)3, AG3FE2(PO4)3, K3CR2(PO4)3, K3FE2(PO4)3

被引：214

作者：

DYVOIRE, F

PINTARDSCREPEL, M

BRETEY, E

DELAROCHERE, M

机构：

[1] Univ de Paris 11 (Paris-Sud), Lab de, Chimie Appliquee, Orsay, Fr, Univ de Paris 11 (Paris-Sud), Lab de Chimie Appliquee, Orsay, Fr

来源：

SOLID STATE IONICS | 1983年 / 9-10卷 / DEC期

关键词：

CRYSTALS - Structure - ELECTROLYTES - Electric Conductivity - ION EXCHANGE - PHOSPHATES - Electric Conductivity;

D O I：

10.1016/0167-2738(83)90101-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phosphates A//3M//2(PO//4)//3 (AMP) with A equals Li, Na, Ag, K and M equals Cr, Fe have been prepared by direct synthesis, flux methods and cation exchange in molten salts. The Li, Na and Ag-compounds are solid electrolytes structurally related to Nasicon or to monoclinic Fe//2(SO//4)//3. The paper reports on their synthesis, crystallographic data, phase transitions, ion exchange properties and ionic conduction.

引用

页码：851 / 857

页数：7

共 30 条

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[9] CRYSTAL-CHEMISTRY OF THE NA1+XZR2-XLX(PO4)3 (L = CR, IN, YB) SOLID-SOLUTIONS
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