BENZO DERIVATIVES OF NITROCYCLOPENTADIENE

被引：14

作者：

KERBER, RC

HODOS, M

机构：

[1] Department of Chemistry, State University of New York at Stony Brook, Stony Brook

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 03期

关键词：

D O I：

10.1021/jo01267a601

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Protonation of the potassium salts of 1-nitroindene and 9-nitrofluorene in water solution occurs fastest at oxygen to yield in both cases the aci tautomers. In nonpolar solvents, aci-1-nitroindene tautomerizes to 3-nitroindene via 1-nitroindene; aci-9-nitrofluorene likewise tautomerizes to 9-nitrofluorene. The aci compounds do not tautomerize in hydroxylic solvents. On treatment with benzoyl chloride, both salts yield stable O-benzoyl derivatives. © 1968, American Chemical Society. All rights reserved.

引用

页码：1169 / &

共 24 条

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