ENANTIOSELECTIVE CATALYSIS .54. HYDROGENATION OF METHYL ACETOACETATE USING NICKEL POWDER MODIFIED WITH NABR/(R,R)-TARTARIC ACID

被引：39

作者：

BRUNNER, H ^{[1
]}

MUSCHIOL, M ^{[1
]}

WISCHERT, T ^{[1
]}

WIEHL, J ^{[1
]}

机构：

[1] WC HERAEUS GMBH HANAU,UNTERNEHMENSBEREICH CHEM,W-6450 HANAU 1,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(00)82369-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Commercial Ni powders, activated with H2 and modified with NaBr/(R,R)-(+)-tartaric acid are heterogeneous catalysts for the enantioselective hydrogenation of methyl acetoacetate (MAA) to give (R)-(-)-methyl 3-hydroxybutanoate (MHB) in up to 76.9% ee. © 1990.

引用

页码：159 / 162

页数：4

共 11 条

[1] BRUNNER H, IN PRESS J ORGANOMET
[2] BRUNNER H, 1988, TOP STEREOCHEM, V18, P129
[3] STUDIES ON MODIFIED HYDROGENATION CATALYST .1. SELECTIVE HYDROGENATION ACTIVITY OF MODIFIED RANEY NICKEL CATALYST FOR CARBONYL GROUP AND C=C DOUBLE BOND
FUKAWA, H
IZUMI, Y
KOMATSU, S
AKABORI, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1962, 35 (10) : 1703 - 1706
[4] IMPROVED MODIFIED RANEY-NICKEL CATALYST FOR ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) HYDROGENATION OF METHYL ACETOACETATE
HARADA, T
IZUMI, Y
[J]. CHEMISTRY LETTERS, 1978, (11) : 1195 - 1196
[5] THE ENANTIOFACE-DIFFERENTIATING (ASYMMETRIC) HYDROGENATION OF THE C=O DOUBLE-BOND WITH MODIFIED RANEY-NICKEL .36. THE DEVELOPMENT OF MODIFIED NICKEL-CATALYSTS WITH HIGH ENANTIOFACE-DIFFERENTIATING ABILITIES
HARADA, T
YAMAMOTO, M
ONAKA, S
IMAIDA, M
OZAKI, H
TAI, A
IZUMI, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (08) : 2323 - 2329
[6] MODIFIED RANEY-NICKEL (MRNI) CATALYST - HETEROGENEOUS ENANTIO-DIFFERENTIATING (ASYMMETRIC) CATALYST
IZUMI, Y
[J]. ADVANCES IN CATALYSIS, 1983, 32 : 215 - 271
[7] ON THE DEPOLYMERIZATION OF POLY-(R)-3-HYDROXY-BUTANOATE (PHB)
SEEBACH, D
ZUGER, M
[J]. HELVETICA CHIMICA ACTA, 1982, 65 (02) : 495 - 503
[8] EMBEDDED NICKEL-CATALYST IN POLYMER
TAI, A
IMACHI, Y
HARADA, T
IZUMI, Y
[J]. CHEMISTRY LETTERS, 1981, (11) : 1651 - 1652
[9] PREPARATION OF DURABLE MODIFIED RANEY-NICKEL CATALYST (MRNI)
TAI, A
TSUKIOKA, K
OZAKI, H
HARADA, T
IZUMI, Y
[J]. CHEMISTRY LETTERS, 1984, (12) : 2083 - 2084
[10] TAI A, 1984, 8TH INT C CAT P, V5

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