NITROCYCLOPROPANES FROM NITRODIAZOMETHANES - PREPARATION AND REACTIVITY

被引：84

作者：

OBANNON, PE ^{[1
]}

DAILEY, WP ^{[1
]}

机构：

[1] UNIV PENN, DEPT CHEM, PHILADELPHIA, PA 19104 USA

来源：

TETRAHEDRON | 1990年 / 46卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(01)89052-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitrodiazo compounds cyclopropanate electron rich alkenes in the presence of rhodium(II) acetate. The yields and diastereoselectivities are dependent on both the alkene and the nitrodiazo precursor. Nitrocyclopropanecarboxylates undergo ring opening, reduction and hydrolysis. © 1990.

引用

页码：7341 / 7358

页数：18

共 70 条

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