MOLECULAR MERCAPTAN (THIOL) COMPLEXES - THE SYNTHESIS OF THE TERT-BUTANETHIOL COMPLEXES [RU(ETA-5-C5H5)(PPH3)(BUTNC)(BUTSH)]PF6 AND [RU(ETA-5-C5H5)(DPPM)(BUTSH)]PF6 AND THE X-RAY SINGLE-CRYSTAL STRUCTURE OF [RU(ETA-5-C5H5)(DPPM)(BUTSH)]PF6 [DPPM = BIS(DIPHENYLPHOSPHINO)METHANE]

被引：17

作者：

CONROYLEWIS, FM ^{[1
]}

SIMPSON, SJ ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 06期

关键词：

D O I：

10.1039/c39910000388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the chlorides [Ru(eta-5-C5H5)(PPh3)(Bu(t)NC)(Cl)] and [Ru(eta-5-C5H5)(dppm)(Cl)] with Bu(t)SH in methanol containing NH4PF6 leads to the isolation of the complexes [Ru(eta-5-C5H5)(PPh3)(Bu(t)NC)(Bu(t)SH)]PF6 2 and [Ru(eta-5-C5H5)(dppm)(Bu(t)SH)]PF6 4 which both contain the intact thiol as a ligand.

引用

页码：388 / 389

页数：2

共 18 条

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