THERMAL AND LIGHT-INDUCED SPIN CROSSOVER TO A METASTABLE LOW-SPIN STATE IN [FE(MTZ)6](CF3SO3)2

被引：25

作者：

GUTLICH, P ^{[1
]}

POGANIUCH, P ^{[1
]}

机构：

[1] BASF AG,AMMONIAKLAB ZAA I,W-6700 LUDWIGSHAFEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 08期

关键词：

D O I：

10.1002/anie.199109751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation by red light at T less-than-or-similar-to 40 K induces the transition of the stable high-spin state of 1 to a metastable low-spin state, which, at T < 40 K, has a lifetime of days to weeks. The transition occurs via double intersystem crossing, 5T2 --> 5E --> 3T1 --> 1A1. Compound 1 is only the second compound to show this effect.

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页码：975 / 977

页数：3

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