OPTICAL-ROTATION MEASUREMENTS OF ORGANOMETALLIC COMPOUNDS - CAVEATS AND RECOMMENDED PROCEDURES

被引：31

作者：

DEWEY, MA ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 06期

关键词：

D O I：

10.1021/om00030a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

There are many possible sources of error in determining specific rotations, [alpha]T(lambda) of chiral, nonracemic organometallic compounds (e.g., purity, sample mass, solution volume, temperature). These are systematically analyzed, and recommended procedures are outlined. Protocols for calculating 95% confidence limits are given.

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页码：2390 / 2392

页数：3

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