EVALUATION OF THE DIPOLE-MOMENTS OF ORGANIC IONS IN THE GAS-PHASE

被引：6

作者：

BORTOLINI, O ^{[1
]}

OLIMPIERI, L ^{[1
]}

TRALDI, P ^{[1
]}

机构：

[1] CNR,SERV SPETTROMETRIA MASSA,I-35100 PADUA,ITALY

来源：

ORGANIC MASS SPECTROMETRY | 1994年 / 29卷 / 06期

关键词：

D O I：

10.1002/oms.1210290602

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dipole moments of a series of substituted benzene radical cations were evaluated on the basis of mass displacements from the expected instrumental value by ion trap experiments. Mass displacements represent a direct measure of the total polarizability, giving access to both the electronic and dipolar polarizabilities, depending on the characteristics of the analyte under investigation. A linear relationship was found between the dipolar polarizabilities and the dipole moments of the corresponding neutrals.

引用

页码：273 / 276

页数：4

共 14 条

[1] ATOM DIPOLE INTERACTION MODEL FOR MOLECULAR POLARIZABILITY - APPLICATION TO POLYATOMIC-MOLECULES AND DETERMINATION OF ATOM POLARIZABILITIES [J].