A NOVEL REACTION OF OS6(CO)18 WITH ME3NO - ISOLATION AND NMR-STUDY OF THE NEW HEXAOSMIUM CLUSTER ANION [HOS6(CO)17]-

被引：12

作者：

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

PEARSALL, MA ^{[1
]}

SCOTT, LG ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)83075-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the absence of a ligand and in non-coordinating solvents, Os6(CO)18 reacts with 2 equivalents of R3NO (R = Me, Et) to give the new hexaosmium cluster [HOs6(CO)17]-. Variable temperature H-1 and C-13 NMR and 2D NMR techniques have been used to investigate the structure of this anion and its dynamic behaviour in solution. The mechanism of the novel reaction is discussed.

引用

页码：C27 / C32

页数：6

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