CATHODIC ISOMERIZATION OF EPOXYSULFIDES EPOXYSULFOXIDES AND EPOXYSULFONES

被引：11

作者：

NIYAZYMBETOV, ME

KONYUSHKIN, LD

NIYAZYMBETOVA, ZI

KALUGIN, VE

LITVINOV, VP

PETROSYAN, VA

机构：

[1] N.D. Zelinsky Institute of Organic Chemistry, USSR Academy of Sciences, Moscow, 117913

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)74498-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It has been established that the electrolysis of 2,3-epoxypropylsulfides, -sulfoxides and -sulfones on Pt or glassy carbon cathodes proceeds via the cleavage of the alpha-C-H bond, followed by intramolecular interaction of the alpha-carbanion with epoxidic ring to give corresponding allylic alcohols in good yields.

引用

页码：1099 / 1102

页数：4