VINYL ANION EQUIVALENT .5. ASYMMETRIC-SYNTHESIS OF ALLYLIC ALCOHOLS USING CHIRAL 2-(TRIALKYLSILYL)ETHYL SULFOXIDES

被引：30

作者：

KUSUDA, S ^{[1
]}

UENO, Y ^{[1
]}

TORU, T ^{[1
]}

机构：

[1] NAGOYA INST TECHNOL,DEPT APPL CHEM,SHOWA KU,NAGOYA,AICHI 466,JAPAN

来源：

TETRAHEDRON | 1994年 / 50卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80816-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the alpha-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.

引用

页码：1045 / 1062

页数：18

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