SYNTHESIS OF NEW CHIRAL CATALYSTS, N-ALKYL-2-AZANORBORNYL-METHANOLS, FOR THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ARYLALDEHYDES

被引：36

作者：

NAKANO, H

KUMAGAI, N

KABUTO, C

MATSUZAKI, H

HONGO, H

机构：

[1] TOHOKU COLL PHARMACEUT SCI,AOBA KU,SENDAI,MIYAGI 981,JAPAN

[2] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 06期

关键词：

D O I：

10.1016/0957-4166(95)00151-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral ligands, 2-azanorbornylmethanols, were prepared and catalyzed the addition of diethylzinc to aldehydes to furnish secondary alcohols in up to 92%ee.

引用

页码：1233 / 1236

页数：4

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