THE EFFECT OF CRYSTALLINITY ON THE PROPERTIES OF INJECTION MOLDED POLYPROPYLENE AND POLYACETAL

被引:70
作者
WRIGHT, DGM [1 ]
DUNK, R [1 ]
BOUVART, D [1 ]
AUTRAN, M [1 ]
机构
[1] ETAB TECH CENT ARMEMENT,F-94114 ARCUEIL,FRANCE
关键词
Acetal Resins--Mechanical Properties - Calorimetry - Heat Treatment--Annealing - Plastics--Injection Molding - Polypropylene--Mechanical Properties;
D O I
10.1016/0032-3861(88)90134-6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of the degree of crystallinity on properties has been studied for two injection molded semicrystalline engineering thermoplastic materials, polypropylene and polyacetal. The differences in the degree of crystallinity were obtained initially by altering the mold temperature and hence and the polymer cooling rate. The effects of (1) annealing and (2) small changes in the melt temperature were also studied. The degree of crystallinity was evaluated by X-ray diffraction and differential scanning calorimetry (d.s.c.). Only small changes in the degree of crystallinity were recorded but considerable differences in microstructures were induced for both polypropylene and polacetal. Tensile and tract properties were measured and area discussed in terms of the microstructural changes in the moldings.
引用
收藏
页码:793 / 796
页数:4
相关论文
共 7 条
[1]  
CLARK ES, 1967, SPE J, V23, P46
[2]   STUDY OF CRYSTALLIZATION AND ISOTHERMAL THICKENING IN POLYETHYLENE USING SAXD, LOW-FREQUENCY RAMAN-SPECTROSCOPY AND ELECTRON-MICROSCOPY [J].
DLUGOSZ, J ;
FRASER, GV ;
GRUBB, D ;
KELLER, A ;
ODELL, JA ;
GOGGIN, PL .
POLYMER, 1976, 17 (06) :471-480
[3]  
HERMANS PH, 1961, MAKROMOL CHEM, V50, P98
[4]   SKIN-CORE MORPHOLOGY AND STRUCTURE-PROPERTY RELATIONSHIPS IN INJECTION-MOLDED POLYPROPYLENE [J].
KANTZ, MR ;
STIGALE, FH ;
NEWMAN, HD .
JOURNAL OF APPLIED POLYMER SCIENCE, 1972, 16 (05) :1249-&
[5]   THE MICROSTRUCTURE OF INJECTION-MOLDED SEMI-CRYSTALLINE POLYMERS - A REVIEW [J].
KATTI, SS ;
SCHULTZ, JM .
POLYMER ENGINEERING AND SCIENCE, 1982, 22 (16) :1001-1017
[6]   MICROSTRUCTURAL ASPECTS OF FAILURE IN SEMICRYSTALLINE POLYMERS [J].
SCHULTZ, JM .
POLYMER ENGINEERING AND SCIENCE, 1984, 24 (10) :770-785
[7]   RAPID SMALL-ANGLE AND WIDE-ANGLE X-RAY STUDIES OF CRYSTALLIZATION BEHAVIOR IN POLYMERS [J].
SCHULTZ, JM .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1976, 14 (12) :2291-2311