RHODIUM(II) PERFLUOROBUTYRATE CATALYZED HYDROSILYLATION OF 1-ALKYNES - TRANS ADDITION AND REARRANGEMENT TO ALLYLSILANES

被引：68

作者：

DOYLE, MP

HIGH, KG

NESLONEY, CL

CLAYTON, TW

LIN, J

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 05期

关键词：

D O I：

10.1021/om00051a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrosilylation of 1-alkynes catalyzed by rhodium(II) perfluorobutyrate or chloroplatinic acid forms either allylsilanes or vinylsilanes in moderate to high isolated yields, dependent on the mode of addition of reactants. The duality of these transformations appears to be dependent on coordination of the organosilane or alkyne with the transition-metal catalyst.

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页码：1225 / 1226

页数：2

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