MANGANESE(II) BASED OXIDATION OF ALKANES - GENERATION OF A HIGH-VALENT BINUCLEAR CATALYST IN-SITU

被引：55

作者：

MENAGE, S ^{[1
]}

COLLOMBDUNANDSAUTHIER, MN ^{[1
]}

LAMBEAUX, C ^{[1
]}

FONTECAVE, M ^{[1
]}

机构：

[1] UNIV GRENOBLE 1,ETUD DYNAM & STRUCT SELECT LAB,URA 332,F-38041 GRENOBLE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001885

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The efficiently Mn2+-catalysed oxidation of saturated hydrocarbons by alkylhydroperoxides or iodosylbenzene in the presence of 2,2'-bipyridine in acetonitrile follows the following pathway: Mn2+ + bipy -->, [Mn(bipy)(3)](2+) --> [Mn2O2(bipy)(4)](3+), the latter being identified as the catalytic species; it affords cyclohexanol and cyclohexanone in equal amounts and the remarkable robustness of the active complex, under oxidative conditions, is noted.

引用

页码：1885 / 1886

页数：2

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