PREPARATION AND STRUCTURE OF CU-II(C2H5PO3) - STRUCTURAL TRANSITION BETWEEN ITS HYDRATED AND DEHYDRATED FORMS

被引：51

作者：

LEBIDEAU, J

BUJOLI, B

JOUANNEAUX, A

PAYEN, C

PALVADEAU, P

ROUXEL, J

机构：

[1] INST MAT NANTES,CNRS,UM 0110,2 RUE HOUSSINIERE,F-44072 NANTES 03,FRANCE

[2] LAB SYNTHESE ORGAN & CHIM ORGAN APPL,CNRS,URA 475,F-44072 NANTES 03,FRANCE

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 21期

关键词：

D O I：

10.1021/ic00073a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of Cu(II)(C2H5PO3) has been solved ab initio using direct methods and refined from X-ray powder diffraction data. This compound is monoclinic, space group P2(1)/c, with a = 10.7773(3) angstrom, b = 5.6960(2) angstrom, c = 7.6273(2) angstrom, beta = 94.47(1)-degrees, Z = 4, and V = 466.8(2) angstrom3. The Rietveld refinement gave R(I) = 0.047, R(p) = 0.107, R(wp) = 0.116, and R(exp) = 0.104. The layers rearrangement between its hydrated and dehydrated form is presented.

引用

页码：4617 / 4620

页数：4

共 21 条

[1] INDEXING OF POWDER DIFFRACTION PATTERNS FOR LOW-SYMMETRY LATTICES BY THE SUCCESSIVE DICHOTOMY METHOD [J].