ATMOSPHERIC GAS-AEROSOL EQUILIBRIUM .3. THERMODYNAMICS OF CRUSTAL ELEMENTS CA2+, K+, AND MG2+

被引：129

作者：

KIM, YP ^{[1
]}

SEINFELD, JH ^{[1
]}

机构：

[1] CALTECH, DEPT CHEM ENGN, PASADENA, CA 91125 USA

来源：

AEROSOL SCIENCE AND TECHNOLOGY | 1995年 / 22卷 / 01期

关键词：

D O I：

10.1080/02786829408959730

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Thermodynamics of the water-soluble crustal ionic species Ca2+, K+, and Mg2+ are added to that of those species already included (Na+, NH4+, Cl-, NO3-, and SO42-) in the gas-particle equilibrium model SCAPE (Kim et al., 1993ab) which estimates the state and composition of atmospheric inorganic species between the gas and aerosol phases. Thermodynamic properties for the aerosol species that include the above ions, equilibrium constants, ionic activity coefficients, water activity, and deliquescence points, are estimated. Various methods for activity coefficient estimation are compared.

引用

页码：93 / 110

页数：18

共 52 条

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