THE SYNTHESIS, CHARACTERIZATION AND MOLECULAR-STRUCTURES OF 2 MIXED-METAL OCTAHEDRAL CARBIDO CLUSTERS, RU5RHC(CO)14(ETA(5)-C5ME5) AND RU5RHC(CO)9(ETA(5)-C5ME5)(ETA(5)-C5H5)2

被引：26

作者：

BAILEY, PJ

BLAKE, AJ

DYSON, PJ

JOHNSON, BFG

LEWIS, J

PARISINI, E

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83187-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ionic coupling between the dianionic ruthenium cluster [Ru5C(CO14]2- and the dicationic rhodium species [Rh(C5 Me5)(MeCN)3]2+ in refluxing CH2Cl2 yields the hexanuclear mixed metal carbido cluster Ru5RhC(CO)14(eta5-C5Me5) (1). Activation of 1 towards reaction with C5H6 or C6H8 by trimethylamine-N-oxide (Me3NO) results in the formation of Ru5RhC (CO)9(eta5-C5Me5)(eta5-C5H5)2 (2) and Ru5RhC(CO)11(eta5-C5Me5)(mu3-eta2:eta2:eta2-C6H6) (3) respectively. Complexes 1 and 2 have been structurally characterized by X-ray diffraction.

引用

页码：175 / 179

页数：5

共 10 条

[1]

BAILEY PJ, 1992, J CHEM SOC DA, P2121

[2] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE [J].