TRIBLOCK COPOLYMERS AND NETWORKS INCORPORATING OLIGO (OXYETHYLENE) CHAINS

被引:37
作者
ALLOIN, F
SANCHEZ, JY
ARMAND, M
机构
[1] Laboratoire d'Ionique et d'Électrochimie du Solide, Domain Universitaire, 38402 Saint-Martin d'Heres Cedex
关键词
3-Chloro-2-chloromethyl-1-propene - Poly(ethylene glycol) - Poly(oxyethylene) - Triblock copolymers;
D O I
10.1016/0167-2738(93)90267-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Linear A-B-A triblock copolymers with an oligo(oxyethylene) central block, and different networks have been synthesized. ac conductivity, electrochemical stability and thermal behaviour of lithium polymer electrolyte based on these materials have been investigated. The more promising host polymer is obtained from step by step reaction of several poly(ethylene glycol) with 3-chloro-2-chloromethyl-1-propene, followed by free-radical cross-linking of the double bonds.
引用
收藏
页码:3 / 9
页数:7
相关论文
共 6 条
[1]   CONDUCTIVITY MEASUREMENTS OF LITFSI TRIBLOCK COPOLYMERS WITH A CENTRAL POE SEQUENCE [J].
ALLOIN, F ;
SANCHEZ, JY ;
ARMAND, MB .
ELECTROCHIMICA ACTA, 1992, 37 (09) :1729-1731
[2]  
ARMAND M, 1989, 2 INT M POL EL, P91
[3]  
BENRABAH D, 1993, IN PRESS FARADAY T
[4]  
CRAVEN JR, 1986, MAKROMOL CHEM-RAPID, V7, P81
[5]  
KOSHAR RJ, 1973, J ORG CHEM, V38, P3358, DOI 10.1021/jo00959a026
[6]   ELECTROCHEMICAL STUDY OF LINEAR AND CROSS-LINKED POE-BASED POLYMER ELECTROLYTES [J].
SYLLA, S ;
SANCHEZ, JY ;
ARMAND, M .
ELECTROCHIMICA ACTA, 1992, 37 (09) :1699-1701