DIASTEREOSELECTIVE INTRODUCTION OF AN ETO(2)CCF(2)-GROUP INTO CHIRAL IMIDE ENOLATES MEDIATED BY TRIETHYLBORANE

被引：20

作者：

ISEKI, K

ASADA, D

TAKAHASHI, M

NAGAI, T

KOBAYASHI, Y

机构：

[1] MEC Laboratory, Daikin Industries, Ltd., Tsukuba, Ibaraki, 305, Miyukigaoka

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 40期

关键词：

D O I：

10.1016/0040-4039(94)85324-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The introduction of an EtO(2)CCF(2)- group into lithium enolates of chiral N-acyloxazolidinones with ethyl difluoroiodoacetate mediated by triethylborane proceeds with good diastereomeric excess (86->98% de).

引用

页码：7399 / 7400

页数：2

共 8 条

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