MILLIMETER-WAVE AND SUBMILLIMETER-WAVE SPECTRUM OF HIGHLY EXCITED-STATES OF WATER

To facilitate studies of water in the interstellar medium and late-type stars, we have measured the frequencies of 30 new millimeter- and submillimeter-wave transitions of H-2 O-16 which lie between 100 GHz and 600 GHz. This represents almost a doubling of the number of water lines that have been observed in the laboratory in this spectral region at high resolution. All of the newly observed lines are highly excited, lying between 2400 and 4200 cm-1 above the ground level. Some of these have large excitation energies because of their high rotational states and others because they lie in excited vibrational states. These lines are potentially of substantial astrophysical significance because they are related to the study of interstellar masers and because their high excitation eliminates the atmospheric self-absorption associated with the more well-known water lines.