EFFECTS OF DOPANT AND SOLVENT ON THE PROPERTIES OF POLYPYRROLE - INVESTIGATIONS WITH CYCLIC VOLTAMMETRY AND ELECTROCHEMICALLY INSITU CONDUCTIVITY

被引：18

作者：

ZHANG, WB ^{[1
]}

DONG, SJ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,ELECTROANALYT CHEM LAB,CHANGCHUN 130022,PEOPLES R CHINA

来源：

ELECTROCHIMICA ACTA | 1993年 / 38卷 / 2-3期

关键词：

POLYPYRROLE; CYCLIC VOLTAMMETRY; INSITU CONDUCTIVITY; NO3-ION; ANION DOPING;

D O I：

10.1016/0013-4686(93)85163-S

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new method for electrochemically in situ conductivity measurements based on a reusable glassy carbon disc carbon fibre array double electrode is described. Using this technique and cyclic voltammetry, we have investigated the effects of the doping anion and solvent on the electrochemical properties of polypyrrole film. The electroactivity and potential dependent conductivity of polypyrrole film are strongly affected by solvent and the doping anion's solubility in the solvent, and also by the history of electrochemical treatments in different electrolyte solutions. It is very interesting that NO3-doped polypyrrole can completely keep its conducting state (doped state) at a reasonably negative potential (eg -0.8 V vs. sce) in acetonitrile solutions.

引用

页码：441 / 445

页数：5

共 13 条

[1] POLYMER-FILMS ON ELECTRODES .13. INCORPORATION OF CATALYSTS INTO ELECTRONICALLY CONDUCTIVE POLYMERS - IRON PHTHALOCYANINE IN POLYPYRROLE [J].