NOVEL RING-OPENING AND HALOGEN TRANSFER FROM PLATINUM(II) TO PHOSPHORUS IN THE REACTION OF [PTCL2(CNR)2] (R = BU-T, P-MEOC6H4) WITH THE PHOSPHIRENE RING PPHCPH=CPH - CRYSTAL AND MOLECULAR-STRUCTURE OF THE DIMERIC CHLOROPHOSPHANE COMPLEX [PTCL(PCLPHCPH=CPH) (CNBU-T)]2

被引：9

作者：

AJULU, FA

HITCHCOCK, PB

MATHEY, F

MICHELIN, RA

NIXON, JF

POMBEIRO, AJL

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

[2] ECOLE POLYTECH,DCPH,CHIM PHOSPHORE & METAUX TRANSIT LAB,F-91128 PALAISEAU,FRANCE

[3] INST SUPER TECN,CTR QUIM ESTRUTURAL,P-1096 LISBON,PORTUGAL

[4] UNIV PADUA,FAC INGN,INST CHIM IND,I-35131 PADUA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of ligating behaviour of the phosphirene ring system PPhCPh=CPh is described, in which novel dimeric platinum(II) chlorophosphane complexes result from phosphirene ring opening and a Pt-Cl bond-insertion reaction.

引用

页码：142 / 143

页数：2

共 9 条

[1] INSERTION REACTIONS OF THE [RHCL(PPH3)2] FRAGMENT INTO A PHOSPHIRENE RING, AND CARBONYLATION OF THE RESULTING RHODIUM(III) COMPLEX - CRYSTAL AND MOLECULAR-STRUCTURES OF [RHCL(PPHCPH=CPH)(PPH3)2], [RHCL(PPHCPH=CPHCO)(PPH3)2] AND THE NOVEL DIMERIC COMPLEX [(RHCL(PPHCPH=CPHCO)(PPH3))2]
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