TEMPERATURE-DEPENDENCE OF THE ENANTIOSELECTIVE HYDROFORMYLATION WITH PTCL2[(S)-BINAP] + SNCL2 CATALYST AND THE DYNAMIC NMR-STUDY OF THE CATALYTIC PRECURSOR

被引：50

作者：

KOLLAR, L

SANDOR, P

SZALONTAI, G

机构：

[1] HUNGARIAN ACAD SCI,CENT CHEM RES INST,H-1525 BUDAPEST,HUNGARY

[2] RES INST HEAVY CHEM IND,H-8201 VESZPREM,HUNGARY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 67卷 / 02期

关键词：

D O I：

10.1016/0304-5102(91)85046-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The strong temperature dependence of the absolute configuration of the alpha-phenylpropanal formed in the PtCl2[(S)-BINAP]-catalysed hydroformylation (BINAP = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) of styrene is explained by the restricted rotation of the phenyl rings on the basis of a dynamic NMR study.

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页码：191 / 198

页数：8

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