CAVITY-SHAPED MOLRACS WITH INWARD-FACING, DIRECT LINE-OF-SIGHT FUNCTIONALITY

被引:13
作者
BUTLER, DN
TEPPERMAN, PM
GAU, RA
WARRENER, RN
WATSON, WH
KASHYAP, RP
机构
[1] CENT QUEENSLAND UNIV,CTR MOLEC ARCHITECTURE,ROCKHAMPTON,QLD 4702,AUSTRALIA
[2] TEXAS CHRISTIAN UNIV,DEPT CHEM,FT WORTH,TX 76129
关键词
D O I
10.1016/0040-4039(95)01164-D
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New rigid cavity molecules are described in which bromides, epoxides, olefins, alcohols and acetates are positioned such that there is direct line of sight between them. Examples are provided of systems where the separation distances are in the range from 4-7 Angstrom, although the principles espoused allow production of molecules with significantly larger separation.
引用
收藏
页码:6145 / 6148
页数:4
相关论文
共 11 条
[1]  
Shimizu, Dewey, Rebek, J. Am. Chem. Soc., 116, pp. 5145-5149, (1994)
[2]  
PaddondashRow, Cotsaris, Patney, The synthesis of rigid norbornylogs for the purpose of studying orbital interactions through bonds, Tetrahedron, 41, (1986)
[3]  
Mitsudo, Naruse, Kondo, Ozaki, Watanabe, Angew. Chemie, Int. Ed., 33, pp. 580-581, (1994)
[4]  
Mitsudo, Kokuryo, Shinsugi, Nakagawa, Watanabe, Takegami, J. Org. Chem., 44, pp. 4492-4496, (1979)
[5]  
Ashton, Girreser, Giuffrida, Kohnke, Mathias, Raymo, Slawin, Stoddart, Williams, J. Amer. Chem. Soc., 115, pp. 5422-5429, (1993)
[6]  
Mantzaris, Weissberger, J. Org. Chem., 39, pp. 726-728, (1974)
[7]  
Traylor, Tsuchiya, Byun, Kim, J. Amer. Chem. Soc., 115, pp. 2775-2781, (1993)
[8]  
Warrener, Groundwater, Pitt, Butler, Russell, Tetrahedron Lett., 32, pp. 1885-1888, (1991)
[9]  
Warrener, Anderson, McCay, PaddondashRow, The preparation of Tricyclo[4,2,1,02,5]nona-3,7-dienes by cycloadditions onto 3,4-disubstituted cyclobutenes. Specificities in the Diels-Alder reaction, Australian Journal of Chemistry, 30, pp. 1481-1507, (1977)
[10]  
Bellucci, Bianchini, Chiappe, Ambrosetti, J. Am. Chem. Soc., 111, pp. 199-202, (1989)