REACTIVITY OF 3,6-DIMETHOXY-3,6-DIMETHYLCYCLOHEXA-1,4-DIENE .2. REGIOSELECTIVE ARYLATION OF ELECTRON-RICH AROMATIC-COMPOUNDS

被引:10
作者
ALONSO, F
YUS, M
机构
[1] Departamento de Quimica Orgánica, Facultad de Ciencias, Universidad de Alicante
关键词
D O I
10.1016/S0040-4020(01)80926-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 3,6-dimethoxy-3,6-dimethylcyclohexa-1,4-diene (1) with electron-rich heterocycles (furan, thiophene, pyrrole, 2-methyl-furan, indole) and 1,3,5-trimethoxybenzene in the presence of catalytic amounts of zinc dichloride or concentrated sulfuric acid leads to the corresponding 2-aryl substituted rho-xylenes 4 in good yields and in a regioselective manner.
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页码:313 / 316
页数:4
相关论文
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