ASYMMETRIC OXIDATION OF D-GLYCERALDEHYDE DIETHYL DITHIOACETAL WITH A SHARPLESS REAGENT

被引：1

作者：

GOMEZ, YA ^{[1
]}

SASTRE, JAL ^{[1
]}

AMO, JFR ^{[1
]}

TEJEDOR, MAS ^{[1
]}

机构：

[1] UNIV VALLADOLID,ETS INGENIEROS IND,DEPT QUIM ORGAN,E-47071 VALLADOLID,SPAIN

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1080/07328309408011846

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The asymmetric oxidation reaction of D-glyceraldehyde diethyl dithioacetal 1 and its di-O-acetyl derivative with a Sharpless reagent to produce the corresponding D-glyceraldehyde diethyl dithioacetal S-oxide derivatives takes place with high stereoselectivity. The configuration of the two new chiral centres formed is deduced.

引用

页码：1051 / 1058

页数：8

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