ETHOXYCARBONYL ACCELERATION OF CYCLOPROPYLCARBINYL RADICAL RING-OPENING

被引：21

作者：

NEWCOMB, M

CHOI, SY

机构：

[1] Department of Chemistry, Wayne State University, Detroit, MI 48202

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 40期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(93)85045-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rate constants for ring opening of the [trans-(2-ethoxycarbonyl)cyclopropyl]methyl radical were determined by competition kinetics employing benzeneselenol trapping.

引用

页码：6363 / 6364

页数：2

共 8 条

[1] THE INVENTION OF NEW RADICAL CHAIN REACTIONS .8. RADICAL CHEMISTRY OF THIOHYDROXAMIC ESTERS - A NEW METHOD FOR THE GENERATION OF CARBON RADICALS FROM CARBOXYLIC-ACIDS
BARTON, DHR
CRICH, D
MOTHERWELL, WB
[J]. TETRAHEDRON, 1985, 41 (19) : 3901 - 3924
[2] KINETICS AND REGIOSELECTIVITY OF RING-OPENING OF SUBSTITUTED CYCLOPROPYLMETHYL RADICALS
BECKWITH, ALJ
BOWRY, VW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (11) : 2681 - 2688
[3] CALIBRATION OF A NEW HOROLOGERY OF FAST RADICAL CLOCKS - RING-OPENING RATES FOR RING-ALKYL-SUBSTITUTED AND ALPHA-ALKYL-SUBSTITUTED CYCLOPROPYLCARBINYL RADICALS AND FOR THE BICYCLO[2.1.0]PENT-2-YL RADICAL
BOWRY, VW
LUSZTYK, J
INGOLD, KU
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) : 5687 - 5698
[4] A CONVENIENT METHOD FOR KINETIC-STUDIES OF FAST RADICAL REARRANGEMENTS - RATE CONSTANTS AND ARRHENIUS FUNCTION FOR THE CYCLOPROPYLCARBINYL RADICAL RING-OPENING
NEWCOMB, M
GLENN, AG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 275 - 277
[5] COMPETITION METHODS AND SCALES FOR ALKYL RADICAL REACTION-KINETICS
NEWCOMB, M
[J]. TETRAHEDRON, 1993, 49 (06) : 1151 - 1176
[6] PICOSECOND RADICAL KINETICS - BENZENESELENOL AS A FAST RADICAL TRAPPING AGENT AND RATE CONSTANTS FOR RING-OPENING OF THE TRANS-(2-PHENYLCYCLOPROPYL)CARBINYL RADICAL
NEWCOMB, M
MANEK, MB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (26) : 9662 - 9663
[7] PICOSECOND RADICAL KINETICS - RING OPENINGS OF PHENYL SUBSTITUTED CYCLOPROPYLCARBINYL RADICALS
NEWCOMB, M
JOHNSON, CC
MANEK, MB
VARICK, TR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10915 - 10921
[8] PICOSECOND RADICAL KINETICS - RATE CONSTANTS FOR REACTION OF BENZENESELENOL WITH PRIMARY ALKYL RADICALS AND CALIBRATION OF THE 6-CYANO-5-HEXENYL RADICAL CYCLIZATION
NEWCOMB, M
VARICK, TR
HA, C
MANEK, MB
YUE, X
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8158 - 8163

← 1 →