NEAR-CRITICAL PHASE-BEHAVIOR OF DILUTE MIXTURES - COMMENT

被引：47

作者：

CHIALVO, AA ^{[1
]}

CUMMINGS, PT ^{[1
]}

机构：

[1] OAK RIDGE NATL LAB,DIV CHEM TECHNOL,OAK RIDGE,TN 37831

来源：

MOLECULAR PHYSICS | 1995年 / 84卷 / 01期

关键词：

D O I：

10.1080/00268979500100031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recently published (Gude, M. T., and Teja, A. S., 1994, Molec. Phys., 81, 599) expression for (partial-derivative/partial-derivativex2)rho,T(infinity) is demonstrated to be valid only at the solvent critical point, and the more general microscopic connection is shown between the isothermal-isochoric finite pressure change (partial-derivativeP/partial-derivativex2)rho,T(infinity) and the rearrangement of the solvent structure around an infinitely dilute solute. Finally, there is discussion of some properties of this derivative and some theoretical implications in the interpretation of solvation at near critical conditions.

引用

页码：41 / 48

页数：8

共 19 条

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